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  • Rights: The University of Waikato
    Published 30 May 2008 Referencing Hub media
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    Prof Richard Haverkamp, of Massey University, outlines the role of electrocatalysts in the production of hydrogen1 from water by electrolysis2.

    Transcript

    DR RICHARD HAVERKAMP
    We’re looking at hydrogen as a new energy carrier, but in order to do that you have to be able to produce the hydrogen and you have to be able to use the hydrogen up. Producing hydrogen by water electrolysis is one way to do it from any electrical energy source. So you might have wave power3 or wind power, to produce the electricity4 and you can make hydrogen from water by putting two electrodes into it and putting some salt5 in there, potassium hydroxide, or sulfuric acid6 or whatever, and electrolyse it and make hydrogen and oxygen7. Now that works perfectly well except that its not very efficient, so you waste a huge proportion of your energy doing it that way. A much better way to do it, is to do it in the cell8 where we have a catalyst9. So rather than just on an electrode10, you have a device set up where the reaction takes place on a catalyst and the catalyst enables the reaction to take place easily, without a lot of waste of energy. And this is an electrocatalyst11 because we‘re using electricity to drive the reaction. A greater proportion of the energy you’re putting in ends up as hydrogen. If you are doing it on a large scale you don't want to waste all your energy, you want to maximise the amount you turn into hydrogen. So we need to have a good electric catalyst for making hydrogen from water. And so we've been working on this material that helps water be converted into hydrogen using electricity in a very efficient way.

    1. hydrogen: First element on the periodic table –­ symbol H, with the atomic number of 1, meaning that it has a single proton in its nucleus.
    2. electrolysis: A chemical change caused by passing electricity through a solution.
    3. power: 1. The rate at which work is done (defined as work divided by time taken). 2. Mechanical or physical energy, force or momentum.
    4. electricity: A general term that includes a variety of phenomena resulting from the presence and flow of electrical charge.
    5. salt: In chemistry, a salt is produced when a strong acid and strong base react. Strong acid + strong base = salt + water.
    6. acid: A hydrogen-containing substance that is capable of donating a hydrogen ion to another substance.
    7. oxygen: A non-metal – symbol O, atomic number 8. Oxygen is a gas found in the air. It is needed for aerobic cellular respiration in cells.
    8. cell: 1. Building block of the body. A human is made of millions of cells, which are adapted for different functions and can reproduce themselves exactly. 2. A simple electrolytic device that enables chemical energy to be transformed into electrical energy.
    9. catalyst: A substance that increases the rate of a chemical reaction but is not permanently changed by that reaction. In living organisms enzymes are catalysts.
    10. electrode: Terminal where electricity goes in or out of a conductor, for example, the positive and negative terminals of a battery.
    11. electrocatalyst: A substance that increases the rate of a chemical reaction that makes or uses electricity.
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      hydrogen

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    2. First element on the periodic table –­ symbol H, with the atomic number of 1, meaning that it has a single proton in its nucleus.

      electricity

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    4. A general term that includes a variety of phenomena resulting from the presence and flow of electrical charge.

      oxygen

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    6. A non-metal – symbol O, atomic number 8. Oxygen is a gas found in the air. It is needed for aerobic cellular respiration in cells.

      electrode

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    8. Terminal where electricity goes in or out of a conductor, for example, the positive and negative terminals of a battery.

      electrolysis

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    10. A chemical change caused by passing electricity through a solution.

      salt

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    12. In chemistry, a salt is produced when a strong acid and strong base react. Strong acid + strong base = salt + water.

      cell

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    14. 1. Building block of the body. A human is made of millions of cells, which are adapted for different functions and can reproduce themselves exactly.

      2. A simple electrolytic device that enables chemical energy to be transformed into electrical energy.

      electrocatalyst

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    16. A substance that increases the rate of a chemical reaction that makes or uses electricity.

      power

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    18. 1. The rate at which work is done (defined as work divided by time taken).

      2. Mechanical or physical energy, force or momentum.

      acid

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    20. A hydrogen-containing substance that is capable of donating a hydrogen ion to another substance.

      catalyst

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    22. A substance that increases the rate of a chemical reaction but is not permanently changed by that reaction. In living organisms enzymes are catalysts.