Add to collection
  • + Create new collection
  • Rights: The University of Waikato. All Rights Reserved.
    Published 30 July 2013 Referencing Hub media
    Download

    Dr Ross Monaghan from AgResearch at Invermay in Otago explains his work in managing the risk of nitrogen1 loss to water systems through the use of nitrification2 inhibitors. Nitrification inhibitors prevent part of the process of the nitrogen cycle3 from occurring – limiting the production of nitrates that can be lost to the environment.

    Jargon alert

    In the nitrogen cycle, gaseous nitrogen enters the soil-plant system via fixation4. In this process, N2 is converted to ammonium5. Through some other steps, ammonium is converted to nitrate6. Nitrate is mobile and gets into waterways through run-offNitrogen inhibitors are chemicals7 that prevent the oxidation8 from ammonium to nitrate taking place, limiting nitrate loss.

    Point of interest

    DCD-based nitrification inhibitors were voluntarily withdrawn from the market in early 2013 after traces were found during routine milk testing. Because DCD is not considered to be a food safety risk, there is no international standard for allowable amounts found in food products. Without this standard, some countries use a default limit of zero. DCD traces in milk are seen as a trade risk rather than a health risk. Ongoing research led by AgResearch scientists has identified a new inhibitor that shows similar efficacy9 to DCD, but without the same risks. The new inhibitor is undergoing longer-term field trials.

    Transcript

    DR ROSS MONAGHAN

    What we’ve been trying to do is manage that risk of nitrogen loss in drainage – we use the term ‘nitrogen leaching’ – and one of the ways is by adding a chemical to our pastures that is either sprayed on as a liquid or applied as a granular product that diffuses through the soil. It’s targeting those urine patches to keep the nitrogen there in the immobile ammonium form.

    Nitrification inhibitors are products that prevent the oxidation of ammonium to nitrite. It appears as though that’s a fairly harmless interference10 in the nitrogen cycle. All it’s doing is keeping the nitrogen in the ammonium form, which the plants can use, and preventing the accumulation of the nitrate, which carries more environmental risk because it can be lost in drainage or as a gaseous form.

    It’s early days in the development of this technology, and what we’ve found is that the inhibitors work well in some places and less well in others, so there’s a lot of research going on to try and allow us to understand what are the main driving factors or influencing variables that will maximise the efficiency and make sure we get good value for money where we apply it.

    Some of the key regional factors that are influencing the effectiveness of the inhibitor are rainfall. Too much rain or too much drainage really washes that inhibitor out of the soil, which means, on the West Coast, it’s hard to keep it in the topsoil where we need it long enough for it to be effective. Another regional factor is temperature11, and what we’ve found is that, where it’s very warm and moist, you have a lot of microbial activity12 in the soil, and those microbes break down the nitrification inhibitor13 relatively quickly.

    So the good news in the south here is that, because it’s relatively cool, not too wet, the inhibitor doesn’t break down or leach14 out of the soil as quickly as in warmer wetter parts of the country. So for the southern South Island at least, it appears as a reasonably cost-effective way of trying to minimise that nitrate leaching15 risk.

    At the moment, the uptake of the nitrification inhibitor16 technology is relatively slow, but that might change in the next 10 or 20 years as the regional councils develop policy that really tries to manage the nitrogen losses that are occurring, and that’s against a backdrop of this on-going intensification of agriculture and land use that is really driven by economic drivers and opportunity.

    Acknowledgements:
    Dr Ross Monaghan, Dr Selai Letica and Belinda Glass, AgResearch, Invermay
    Professor Louis Schipper

    1. nitrogen: A non-metal – symbol N, atomic number 7. Nitrogen is essential for life. It is a component of many molecules that make up cells, including DNA and proteins.
    2. nitrification: Part of the nitrogen cycle. A process that takes place in the soil where bacteria convert ammonium into nitrites and then nitrites into nitrates.
    3. nitrogen cycle: The process by which nitrogen passes through the ecosystem.
    4. fixation: The process of converting atmospheric nitrogen (dinitrogen gas, N2) to forms that can be used by plants and animals to carry out many of the functions of life.
    5. ammonium: NH4+. Derived from ammonia by combination with a hydrogen ion. A nitrogen compound taken up by plants from soils.
    6. nitrate: A chemical composed of three oxygen atoms for every nitrogen atom.
    7. chemicals: Everything is made up of chemicals. All matter (anything made of atoms) can be called chemicals. They can be in any form – liquid, solid or gas. Chemicals can be a pure substance or a mixture.
    8. oxidation: Any chemical process involving the removal of electrons from an element or compound.
    9. efficacy: The ability to produce a desired or intended result.
    10. interference: The simultaneous presence of two or more waves in the same position, resulting in a new wave pattern.
    11. temperature: A measure of the degree of hotness or coldness of an object or substance. Temperature is measured with a thermometer calibrated in one or more temperature scales. Kelvin scale temperature is a measure of the average energy of the molecules of a body.
    12. microbial activity or processes: The metabolic activities of microorganisms resulting in chemical or physical changes.
    13. nitrification inhibitor: Chemical compounds or natural processes that prevent the oxidation of ammonium to nitrite. It inhibits the enzyme activity in microbes responsible for the transformation of ammonium to nitrite and nitrate, keeping nitrogen in the ammonium form, where it is available for plant use.
    14. leaching: When a compound becomes dissolved in water and moves from one place to another, for example, a fertiliser in the soil dissolves in rain water and ends up in a stream.
    15. nitrate leaching: The movement of nitrate from the soil into groundwater. This is an environmental concern because nitrate in groundwater can pollute streams.
    16. nitrification inhibitor: Chemical compounds or natural processes that prevent the oxidation of ammonium to nitrite. It inhibits the enzyme activity in microbes responsible for the transformation of ammonium to nitrite and nitrate, keeping nitrogen in the ammonium form, where it is available for plant use.
      Go to full glossary
      Download all

      nitrogen

    1. + Create new collection
    2. A non-metal – symbol N, atomic number 7. Nitrogen is essential for life. It is a component of many molecules that make up cells, including DNA and proteins.

      fixation

    3. + Create new collection
    4. The process of converting atmospheric nitrogen (dinitrogen gas, N2) to forms that can be used by plants and animals to carry out many of the functions of life.

      chemicals

    5. + Create new collection
    6. Everything is made up of chemicals. All matter (anything made of atoms) can be called chemicals. They can be in any form – liquid, solid or gas. Chemicals can be a pure substance or a mixture.

      interference

    7. + Create new collection
    8. The simultaneous presence of two or more waves in the same position, resulting in a new wave pattern.

      nitrification inhibitor

    9. + Create new collection
    10. Chemical compounds or natural processes that prevent the oxidation of ammonium to nitrite. It inhibits the enzyme activity in microbes responsible for the transformation of ammonium to nitrite and nitrate, keeping nitrogen in the ammonium form, where it is available for plant use.

      nitrification

    11. + Create new collection
    12. Part of the nitrogen cycle. A process that takes place in the soil where bacteria convert ammonium into nitrites and then nitrites into nitrates.

      ammonium

    13. + Create new collection
    14. NH4+. Derived from ammonia by combination with a hydrogen ion. A nitrogen compound taken up by plants from soils.

      oxidation

    15. + Create new collection
    16. Any chemical process involving the removal of electrons from an element or compound.

      temperature

    17. + Create new collection
    18. A measure of the degree of hotness or coldness of an object or substance. Temperature is measured with a thermometer calibrated in one or more temperature scales. Kelvin scale temperature is a measure of the average energy of the molecules of a body.

      leaching

    19. + Create new collection
    20. When a compound becomes dissolved in water and moves from one place to another, for example, a fertiliser in the soil dissolves in rain water and ends up in a stream.

      nitrogen cycle

    21. + Create new collection
    22. The process by which nitrogen passes through the ecosystem.

      nitrate

    23. + Create new collection
    24. A chemical composed of three oxygen atoms for every nitrogen atom.

      efficacy

    25. + Create new collection
    26. The ability to produce a desired or intended result.

      microbial activity or processes

    27. + Create new collection
    28. The metabolic activities of microorganisms resulting in chemical or physical changes.

      nitrate leaching

    29. + Create new collection
    30. The movement of nitrate from the soil into groundwater. This is an environmental concern because nitrate in groundwater can pollute streams.