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  • Rights: The University of Waikato Te Whare Wānanga o Waikato
    Published 30 July 2013 Referencing Hub media
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    Dr Selai Letica explains some of the causes of nitrous oxide1 emissions in agricultural soils and why it is important to limit them.

    Points of interest:

    • Nitrous oxide (N2O) occurs naturally in the environment, but human activities increase its concentration in the atmosphere2.
    • One unit of N2O is equivalent to 310 units of CO2, making nitrous oxide a more potent greenhouse gas3 than CO2.

    Transcript

    DR SELAI LETICA

    Primarily, my research is about finding out how we can reduce nitrous oxide emissions through the use of nitrification4 inhibitors. My research is also concerned with trying to understand the causes of nitrous oxide emissions from agricultural soils. So that’s looking at the relationship between nitrous oxide emissions and things like soil moisture conditions5, nitrogen6 soil levels as well, and a bunch of soil physical conditions as well – the level of compaction7 under dairy cows or dry stock like sheep and beef. Also there’s a spatial component, so understanding where in the paddock nitrous oxide emissions are most likely to come from.

    Nitrous oxide is a really potent greenhouse gas. If you took say 1 kg of carbon dioxide8 and 1 kg of nitrous oxide, that 1 kg of nitrous oxide has nigh on 300 times the global warming potential9 than that same block of carbon dioxide has. So it’s produced in smaller amounts for sure, but what is produced has quite a potential to affect global warming.

    In agriculture, nitrous oxide emissions generally occur in a New Zealand setting from the paddocks. That’s because, when stock are grazing on paddocks, where they deposit their urine and dung, they create massive concentrations of nitrogen in the form of urea10 on the paddock surface. Now, there’s more nitrogen in that urine patch than the plants are able to take up, absorb and use to grow, so that excess nitrogen becomes available for the nitrogen cycle11 to process that urea form of nitrogen into highly mobile forms like nitrate12 or can be lost through the process of denitrification13 to nitrous oxide emissions.

    Acknowledgements
    Dr Selai Letica, AgResearch, Invermay

    1. nitrous oxide: N2O. A naturally occurring atmospheric gas. It is used as a mild anaesthetic and as a fuel. It is also a greenhouse gas.
    2. atmosphere: 1. The layer of gas around the Earth. 2. (atm) A non-SI unit of pressure equivalent to 101.325 kPa.
    3. greenhouse gases: A natural or manmade gas that traps heat in the Earth's atmosphere and contributes to the greenhouse effect. The main greenhouse gases are water vapour, carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), ozone and industrial gases such as chlorofluorocarbons (CFCs). These gases in the Earth's atmosphere trap warmth from the Sun and make life possible. An overabundance of greenhouse gases leads to a rise in global temperatures – known as the greenhouse effect.
    4. nitrification: Part of the nitrogen cycle. A process that takes place in the soil where bacteria convert ammonium into nitrites and then nitrites into nitrates.
    5. condition: An existing state or situation; a mode or state of being.
    6. nitrogen: A non-metal – symbol N, atomic number 7. Nitrogen is essential for life. It is a component of many molecules that make up cells, including DNA and proteins.
    7. compaction: A geologic process in which sediments are progressively buried by more sediment, causing them to press together under their own weight, reducing their thickness.
    8. carbon dioxide: CO2 is a colourless, odourless, incombustible gas. It is a product of cellular respiration and combustion and is an essential component in photosynthesis.
    9. global warming potential (GWP): A measure of how much energy the emissions of 1 ton of a gas will absorb over a given period of time (usually 100 years) relative to the emissions of 1 ton of CO2. Carbon dioxide has a GWP of 1. Nitrous oxide has a GWP of 296. GWP was developed to allow comparisons of the global warming impact of different gases.
    10. urea: A chemical compound found in urine. It is a concentrated nitrogen source and is manufactured artificially for use in fertilisers.
    11. nitrogen cycle: The process by which nitrogen passes through the ecosystem.
    12. nitrate: A chemical composed of three oxygen atoms for every nitrogen atom.
    13. denitrification: Part of the nitrogen cycle. A process where bacteria in soil breaks down nitrates into atmospheric nitrogen gas.
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      nitrous oxide

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    2. N2O. A naturally occurring atmospheric gas. It is used as a mild anaesthetic and as a fuel. It is also a greenhouse gas.

      nitrification

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    4. Part of the nitrogen cycle. A process that takes place in the soil where bacteria convert ammonium into nitrites and then nitrites into nitrates.

      compaction

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    6. A geologic process in which sediments are progressively buried by more sediment, causing them to press together under their own weight, reducing their thickness.

      urea

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    8. A chemical compound found in urine. It is a concentrated nitrogen source and is manufactured artificially for use in fertilisers.

      denitrification

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    10. Part of the nitrogen cycle. A process where bacteria in soil breaks down nitrates into atmospheric nitrogen gas.

      atmosphere

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    12. 1. The layer of gas around the Earth.

      2. (atm) A non-SI unit of pressure equivalent to 101.325 kPa.

      condition

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    14. An existing state or situation; a mode or state of being.

      carbon dioxide

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    16. CO2 is a colourless, odourless, incombustible gas. It is a product of cellular respiration and combustion and is an essential component in photosynthesis.

      nitrogen cycle

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    18. The process by which nitrogen passes through the ecosystem.

      greenhouse gases

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    20. A natural or manmade gas that traps heat in the Earth's atmosphere and contributes to the greenhouse effect. The main greenhouse gases are water vapour, carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), ozone and industrial gases such as chlorofluorocarbons (CFCs). These gases in the Earth's atmosphere trap warmth from the Sun and make life possible. An overabundance of greenhouse gases leads to a rise in global temperatures – known as the greenhouse effect.

      nitrogen

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    22. A non-metal – symbol N, atomic number 7. Nitrogen is essential for life. It is a component of many molecules that make up cells, including DNA and proteins.

      global warming potential (GWP)

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    24. A measure of how much energy the emissions of 1 ton of a gas will absorb over a given period of time (usually 100 years) relative to the emissions of 1 ton of CO2. Carbon dioxide has a GWP of 1. Nitrous oxide has a GWP of 296. GWP was developed to allow comparisons of the global warming impact of different gases.

      nitrate

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    26. A chemical composed of three oxygen atoms for every nitrogen atom.