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    Published 5 October 2012 Referencing Hub media
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    Dr Steve Hood explains that, by viewing a thin section of limestone1 rock through a petrographic microscope2, detailed information about its origin and composition is revealed. Further information can be obtained by using a technique called cathodoluminescence. In seep carbonate work, it allows the calcium carbonate minerals, aragonite3 and calcite4, to be identified by the colours that they emit.

    Point of interest
    Look for this micrograph5

    • Micrograph a: Thin section image of a cold-seep carbonate as seen under cathodoluminescent light. The blue regions indicate the presence of aragonite and the red/pink regions calcite.

    Transcript

    DR STEVE HOOD
    We initially start at the field, we describe what we can see, certainly the big fossils that are visible.

    We then need to take a sample – so we can only do so much in the field – we bring it back to the lab. We then use a saw to slab it or cut it open, and from that, we get a lot more detail visible to us on a fresh unweathered surface.

    We mount it on a glass slide, a microscope slide, and we grind it down so it’s very thin so light can pass through it. And we’d put that on a traditional petrographic microscope to be able to see what’s inside the seep limestone in fine detail – what are some of the cement fabrics, crystals, mineralogies, timing of different growths of cement and some of the organisms that are there.

    We can establish a sequence of events. Just like a tree grows with a logical sequence of bands, often you can discern the first event and work outwards if you like, through the rock section and pick up the different events that have occurred throughout the history of the rock.

    Cathodoluminescence is a specialist petrographic technique. We put our little glass slide, our thin section as we call it, in a vacuum6 chamber which sits on a traditional petrographic microscope, and instead of using a traditional sort of light source like a bulb7 and a lamp, we fire an electron8 beam at our sample in the vacuum chamber and different minerals respond to this energy source by emitting visible light, and some minerals emit different colours. Therefore, particularly for seep carbonate work, it’s easy to identify where aragonite is versus calcite, for example, which is very important in terms of unravelling the history of cementation9 of these deposits.

    Acknowledgement:
    Associate Professor Kathleen Campbell, University of Auckland

    1. limestone: Sedimentary rocks formed mainly from the minerals calcite or dolomite. Many limestones are derived from the shells of dead marine organisms. Others are formed by chemical precipitation.
    2. microscope: An instrument that uses a lens or a series of lenses to magnify small objects.
    3. aragonite: A mineral form of crystalline calcium carbonate similar to calcite. It is found in the shells of marine invertebrates such as pāua and in living coral reefs.
    4. calcite: The most common and most stable mineral form of calcium carbonate (CaCO3). It is the main component of chalk, limestone and marble.
    5. micrograph: A digital image or photograph that represents the view through a microscope.
    6. vacuum: An absence of matter. In practice, a space that contains a very low density of matter (very low pressure) is often referred to as a vacuum.
    7. bulb: A circuit component used to transform electrical energy into light energy. Heat energy is also formed in this process.
    8. electron: A light subatomic particle with negative charge, found in the space surrounding an atomic nucleus.
    9. cementation: A geologic process in which dissolved minerals precipitate out of solution, gluing particles of sediment together.
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      limestone

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    2. Sedimentary rocks formed mainly from the minerals calcite or dolomite. Many limestones are derived from the shells of dead marine organisms. Others are formed by chemical precipitation.

      calcite

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    4. The most common and most stable mineral form of calcium carbonate (CaCO3). It is the main component of chalk, limestone and marble.

      bulb

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    6. A circuit component used to transform electrical energy into light energy. Heat energy is also formed in this process.

      microscope

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    8. An instrument that uses a lens or a series of lenses to magnify small objects.

      micrograph

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    10. A digital image or photograph that represents the view through a microscope.

      electron

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    12. A light subatomic particle with negative charge, found in the space surrounding an atomic nucleus.

      aragonite

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    14. A mineral form of crystalline calcium carbonate similar to calcite. It is found in the shells of marine invertebrates such as pāua and in living coral reefs.

      vacuum

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    16. An absence of matter. In practice, a space that contains a very low density of matter (very low pressure) is often referred to as a vacuum.

      cementation

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    18. A geologic process in which dissolved minerals precipitate out of solution, gluing particles of sediment together.